A few corrosion-resistant iron
artifacts survive from antiquity. A famous (and very
large) example is the Iron Pillar of Delhi, erected by
order of Kumara Gupta I around the year AD 400. However,
unlike stainless steel, these artifacts owe their
durability not to chromium, but to their high phosphorus
content, which together with favorable local weather
conditions promotes the formation of a solid protective
passivation layer of iron oxides and phosphates, rather
than the non-protective, cracked rust layer that
develops on most ironwork.
The corrosion resistance of
iron-chromium alloys was first recognized in 1821 by the
French metallurgist Pierre Berthier, who noted their
resistance against attack by some acids and suggested
their use in cutlery. However, the metallurgists of the
19th century were unable to produce the combination of
low carbon and high chromium found in most modern
stainless steels, and the high-chromium alloys they
could produce were too brittle to be of practical
interest.
This situation changed in
the late 1890s, when Hans Goldschmidt of Germany
developed an aluminothermic (thermite) process for
producing carbon-free chromium. In the years 1904¡V1911,
several researchers, particularly Leon Guillet of
France, prepared alloys that would today be considered
stainless steel. In 1911, Philip Monnartz of Germany
reported on the relationship between the chromium
content and corrosion resistance of these alloys.
Harry Brearley of the
Brown-Firth research laboratory in Sheffield, England is
most commonly credited as the "inventor" of stainless
steel. In 1913, while seeking an erosion-resistant alloy
for gun barrels, he discovered and subsequently
industrialized a martensitic stainless steel alloy.
However, similar industrial developments were taking
place contemporaneously at the Krupp Iron Works in
Germany, where Eduard Maurer and Benno Strauss were
developing an austenitic alloy (21% chromium, 7%
nickel), and in the United States, where Christian
Dantsizen and Frederick Becket were industrializing
ferritic stainless.