A tetravalent metalloid,
silicon is less reactive than its chemical analog carbon. It is the
second most abundant element in the Earth's crust, making up 25.7% of it
by weight. It occurs in clay, feldspar, granite, quartz and sand, mainly
in the form of silicon dioxide (also known as silica) and as silicates,
(various compounds containing silicon, oxygen and one or another metal).
Silicon is the principal component of most semiconductor devices and, in
the form of siliica and silicates, in glass,
cement,
ceramics.
It is also a component of
silicones, a name for various plastic substances often confused with
silicon itself. Silicon is widely used in semiconductors because it has
a lower
reverse leakage current than the semiconductor
Germanium, and because its
native oxide is easily grown in a furnace and forms a better
semiconductor/dielectric interface than almost all other material
combinations.
Notable characteristics:In its
crystalline form, silicon has a dark gray color and a metallic
luster. Even though it is a relatively inert element, silicon still
reacts with
halogens
and dilute
alkalis, but most
acids
(except for a combination of
nitric acid and
hydrofluoric acid) do not affect it. Elemental silicon transmits
more than 95% of all
wavelengths of infrared light. Pure silicon has a negative
temperature co-efficient of
resistance, since the number of free charge carriers increases with
temperature. The electrical resistance of single crystal silicon
significantly changes under the application of mechanical stress due to
the
piezoresistive effect.
Applications:Silicon is a very useful element that is vital
to many human industries.
Silicon and
alloys:
-
The largest application of pure silicon
(metallurgical grade silicon) is in aluminium -
silicon alloys, often called "light alloys", to
produce cast parts, mainly for automotive industry
(this represents about 55 % of the world consumption
of pure silicon).
-
The second largest application of pure silicon
is as a raw material in the production of
silicones (about 40 % of the world consumption
of silicon)
-
Pure silicon is also used to produce ultrapure
silicon for electronic and
photovoltaic applications :
-
Semiconductor - Ultrapure silicon can be
doped with other elements to adjust its
electrical response by controlling the number
and charge (positive
or
negative) of current carriers. Such control
is necessary for
transistors,
solar cells,
semiconductor detectors and other
semiconductor devices which are used in
electronics and other high-tech applications.
-
Photonics - Silicon can be used as a
continuous wave raman
laser to produce coherent light with a
wavelength of 1,698 nm.
-
LCDs and
solar cells -
Hydrogenated amorphous silicon has shown
promise in the production of low-cost,
large-area electronics in applications such
as LCDs. It has also shown promise for
large-area, low-cost solar cells.
-
Steel and cast iron - Silicon is an important
constituent of some steels, and it is used in the
production process of cast iron. It is introduced as
ferro-silicon or silico-calcium
alloys
|
14 |
aluminium ¡ö silicon
¡÷
phosphorus |
|
General |
Name,
Symbol,
Number |
silicon, Si, 14 |
Chemical series |
metalloids |
Group,
Period,
Block |
14,
3, p |
Appearance |
dark gray, bluish tinge |
Atomic mass |
28.0855(3)
g/mol |
Electron configuration |
[Ne] 3s2
3p2 |
Electrons per
shell |
2, 8, 4 |
Physical
properties |
Phase |
solid |
Density (near
r.t.) |
2.33 g/cm³ |
Liquid
density
at
m.p. |
2.57 g/cm³ |
Melting point |
1687 K
(1414 ¢XC,
2577 ¢XF) |
Boiling point |
3538 K
(3265 ¢XC,
5909 ¢XF) |
Heat of fusion |
50.21
kJ/mol |
Heat of vaporization |
359
kJ/mol |
Heat capacity |
(25 ¢XC) 19.789 J/(mol¡PK) |
Vapor pressure
P/Pa |
1 |
10 |
100 |
1 k |
10 k |
100 k |
at T/K |
1908 |
2102 |
2339 |
2636 |
3021 |
3537 |
|
Atomic
properties |
Crystal structure |
Face-centered cubic |
Oxidation states |
4
(amphoteric
oxide) |
Electronegativity |
1.90 (Pauling
scale) |
Ionization energies |
1st: 786.5
kJ/mol |
2nd: 1577.1 kJ/mol |
3rd: 3231.6 kJ/mol |
Atomic radius |
110 pm |
Atomic radius (calc.) |
111
pm |
Covalent radius |
111
pm |
Van der Waals radius |
210
pm |
Miscellaneous |
Magnetic ordering |
nonmagnetic |
Thermal conductivity |
(300 K) 149
W/(m¡PK) |
Thermal expansion |
(25 ¢XC) 2.6 µm/(m¡PK) |
Speed of sound (thin rod) |
(20 ¢XC) 2200
m/s |
Young's modulus |
47 GPa |
Bulk modulus |
100 GPa |
Mohs hardness |
6.5 |
CAS registry number |
7440-21-3 |
Notable
isotopes |
Main article:
Isotopes of silicon
iso |
NA |
half-life |
DM |
DE (MeV) |
DP |
28Si |
92.23% |
Si is
stable with 14
neutrons |
29Si |
4.67% |
Si is
stable with 15
neutrons |
30Si |
3.1% |
Si is
stable with 16
neutrons |
32Si |
syn |
132
y |
£]- |
0.221 |
32P |
|
¡@ |
|